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2026 | Articles and Reviews
Bidentate Versus Monodentate Phosphines on Nickel Phosphide Nanoparticles for the Semi-Hydrogenation of Phenylacetylene at 0 °C
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This study investigates how phosphine ligand structure, specifically monodentate versus bidentate coordination, affects the low-temperature hydrogenation of phenylacetylene catalyzed by nickel phosphide nanoparticles. While as-prepared nanoparticles show no activity at 0 °C, adding carefully selected phosphine ligands enables partial conversion to styrene with complete selectivity. Sixteen phosphines were screened to assess how steric and electronic factors tune surface reactivity. |
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K. Bakkouche, S. Carenco, ChemNanoMat 2026, DOI 10.1002/cnma.70321 |
